Electrochemical properties of [MnIII(terpy)(N3)3] (terpy=2,2′:6′,2″-terpyridine) in CH3CN Electrogeneration of dimanganese(II) di-μ-azido and dimanganese(IV) di-μ-oxo complexes
Baffert C, Chen H, Crabtree R, Brudvig G, Collomb M. Electrochemical properties of [MnIII(terpy)(N3)3] (terpy=2,2′:6′,2″-terpyridine) in CH3CN Electrogeneration of dimanganese(II) di-μ-azido and dimanganese(IV) di-μ-oxo complexes. Journal Of Electroanalytical Chemistry 2001, 506: 99-105. DOI: 10.1016/s0022-0728(01)00488-0.Peer-Reviewed Original ResearchQuasi-reversible reduction waveQuasi-reversible oxidation waveTetra-n-butylammonium perchlorateElectron paramagnetic resonance spectroscopyControlled-potential reductionOne-electron wavesDi-μ-azidoControlled-potential oxidationParamagnetic resonance spectroscopyExhaustive electrolysesM Bu4NClO4New mononuclearOxidation waveElectrochemical propertiesRedox coupleCH3CN solutionCyclic voltammogramsElectrochemical behaviorReduction waveAzide complexesReduced speciesQuantitative conversionOxidation processResonance spectroscopyResidual H2O