Functional Manganese Model Chemistry Relevant to the Oxygen-Evolving Complex of Photosystem II: Oxidation of a Mn(III,IV) Complex Coupled to Deprotonation of a Terminal Water Ligand
Cady C, Crabtree R, Brudvig G. Functional Manganese Model Chemistry Relevant to the Oxygen-Evolving Complex of Photosystem II: Oxidation of a Mn(III,IV) Complex Coupled to Deprotonation of a Terminal Water Ligand. 2008, 377-381. DOI: 10.1007/978-1-4020-6709-9_85.Peer-Reviewed Original ResearchTerminal water ligandsWater ligandsDinuclear manganese complexPH-dependent oxidationOxygen-Evolving ComplexRedox stepsManganese complexesRedox levelingElectron transferModel chemistryTerminal waterLigandsOxidationDeprotonationComplex occursComplexesPhotosystem IIChemistryProtonsMVPHWaterNarrow rangeTransfer