2023
Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two‐Dimensional Metal–Organic Frameworks
Wang D, Ostresh S, Streater D, He P, Nyakuchena J, Ma Q, Zhang X, Neu J, Brudvig G, Huang J. Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two‐Dimensional Metal–Organic Frameworks. Angewandte Chemie 2023, 135 DOI: 10.1002/ange.202309505.Peer-Reviewed Original ResearchTransient absorption spectroscopyX-ray transient absorption spectroscopyPhotoelectric devicesAbsorption spectroscopyOptical transient absorption spectroscopyTime-resolved terahertz spectroscopyHigh photoconductivityHole transport mechanismTwo-dimensional metalsElectron dynamicsDensity functional theory calculationsTerahertz spectroscopyElectronic statesFunctional theory calculationsMetal-organic frameworksPhotoconductivityTheory calculationsCharge transportMobile chargesSpectroscopyHole transport pathwaysCharge transport pathwaysDominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two‐Dimensional Metal–Organic Frameworks
Wang D, Ostresh S, Streater D, He P, Nyakuchena J, Ma Q, Zhang X, Neu J, Brudvig G, Huang J. Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two‐Dimensional Metal–Organic Frameworks. Angewandte Chemie International Edition 2023, 62: e202309505. PMID: 37872121, DOI: 10.1002/anie.202309505.Peer-Reviewed Original ResearchTransient absorption spectroscopyX-ray transient absorption spectroscopyPhotoelectric devicesAbsorption spectroscopyOptical transient absorption spectroscopyTime-resolved terahertz spectroscopyHigh photoconductivityHole transport mechanismTwo-dimensional metalsElectron dynamicsDensity functional theory calculationsTerahertz spectroscopyElectronic statesFunctional theory calculationsMetal-organic frameworksPhotoconductivityTheory calculationsCharge transportMobile chargesSpectroscopyHole transport pathwaysCharge transport pathways
2021
Photoinduced Charge Transport in Conductive Metal Organic Frameworks
Ostresh S, Nyakuchena J, Pattenale B, Neu J, Streater D, Fiankor C, Hu W, Kinigstein E, Zhang J, Zhang X, Schmuttenmaer C, Huang J, Brudvig G. Photoinduced Charge Transport in Conductive Metal Organic Frameworks. 2021, 00: 1-2. DOI: 10.1109/irmmw-thz50926.2021.9567551.Peer-Reviewed Original ResearchConductive metal-organic frameworksMetal-organic frameworksPhotocatalytic applicationsCharge transport mechanismOrganic frameworksPorous crystalline materialsCharge transportTerahertzCrystalline materialsTransport mechanismRational designPromising classConductivityApplicationsAbsorption spectroscopyTransient absorption spectroscopyMaterials
2016
Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer
Brennan B, Regan K, Durrell A, Schmuttenmaer C, Brudvig G. Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer. ACS Energy Letters 2016, 2: 168-173. DOI: 10.1021/acsenergylett.6b00583.Peer-Reviewed Original ResearchPropylene carbonateRedox-active monolayerCharge transfer kineticsAqueous solvent mixturesCharge transfer mechanismLateral charge transferLateral charge transportPorphyrin monolayersPorphyrin systemsCharge transferSolvent dependenceInfluence of waterSolar energy harvestingSolvent mixturesCharge transportSolventHole hoppingPacking dynamicsMonolayersOrders of magnitudeCarbonateNsSolvationWater