2021
Forging O–O Bonds
Cody C, Brudvig G. Forging O–O Bonds. Joule 2021, 5: 1923-1925. DOI: 10.1016/j.joule.2021.07.013.Peer-Reviewed Original Research
2020
Synthesis of organometallic pincer-supported cobalt(II) complexes
Townsend T, Bernskoetter W, Brudvig G, Hazari N, Lant H, Mercado B. Synthesis of organometallic pincer-supported cobalt(II) complexes. Polyhedron 2020, 177: 114308. DOI: 10.1016/j.poly.2019.114308.Peer-Reviewed Original Research
2017
Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O‐Donor Organic Ligand
Sharninghausen L, Sinha S, Shopov D, Mercado B, Balcells D, Brudvig G, Crabtree R. Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O‐Donor Organic Ligand. Angewandte Chemie 2017, 129: 13227-13231. DOI: 10.1002/ange.201707593.Peer-Reviewed Original ResearchCoordination complexesO-donor organic ligandsMononuclear coordination complexesO-donor environmentMetal-centered oxidationX-ray crystallographyOrganic ligandsDonor strengthAlkoxide groupsDFT calculationsD orbitalsUnprecedented stabilityComplexesLigandsOxidationIR-VIsomersXPSCrystallographyV complexSynthesisCharacterizationStabilityCalculationsDegradation
2011
An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst
Brewster T, Blakemore J, Schley N, Incarvito C, Hazari N, Brudvig G, Crabtree R. An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst. Organometallics 2011, 30: 965-973. DOI: 10.1021/om101016s.Peer-Reviewed Original ResearchWater oxidation catalystsOne-electron stepsX-ray crystallographyWingtip groupsElectrochemical characterizationLigand environmentElectrochemical behaviorOxidation stateEPR spectroscopyNew compoundsCatalystRhombic symmetryCompoundsΚ2 CC donorsPrecatalystNHCChelatesCrystallographySpectroscopyLigandsCatalyticPrecursorsCharacterizationWater
1988
ChemInform Abstract: Modeling the Oxygen‐Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex.
KULAWIEC R, CRABTREE R, BRUDVIG G, SCHULTE G. ChemInform Abstract: Modeling the Oxygen‐Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex. ChemInform 1988, 19: no-no. DOI: 10.1002/chin.198832235.Peer-Reviewed Original Research