Selective Methane Oxidation by Heterogenized Iridium Catalysts
Li H, Fei M, Troiano J, Ma L, Yan X, Tieu P, Yuan Y, Zhang Y, Liu T, Pan X, Brudvig G, Wang D. Selective Methane Oxidation by Heterogenized Iridium Catalysts. Journal Of The American Chemical Society 2023, 145: 769-773. PMID: 36594824, DOI: 10.1021/jacs.2c09434.Peer-Reviewed Original ResearchConceptsSelective methane oxidationValue-added oxygenatesPrepared catalystIr complexesIr centerOxide supportIridium catalystEasy separationC bondDirect CHImmobilization approachCatalystMethyl migrationOH productionMethane oxidationAcetic acidDirect routeKey stepCHCarbonylationElectrophilicityOxygenatesCarbonylBondsOxidation