2024
Selecting between Ammonia and Water Oxidation: Electrochemical Oxidation of Ammonia in Water Using an Organometallic–Inorganic Hybrid Anode
Liu H, Jayworth J, Crabtree R, Brudvig G. Selecting between Ammonia and Water Oxidation: Electrochemical Oxidation of Ammonia in Water Using an Organometallic–Inorganic Hybrid Anode. ACS Catalysis 2024, 14: 2842-2846. DOI: 10.1021/acscatal.3c05899.Peer-Reviewed Original ResearchHybrid anodeWater oxidationBlue layerElectrochemical oxidation of ammoniaOxidation of ammoniaElectrochemical oxidationSurface poisoningAqueous solventAmmonia oxidationOptimal operating conditionsAqueous solutionAmbient conditionsE appOperating conditionsAnodeFormation of nitriteOxidationOptimum selectionAmmoniaSolventNitrateNanoclustersDinitrogenElectrodeEcofriendly products
2011
A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst
Moore G, Blakemore J, Milot R, Hull J, Song H, Cai L, Schmuttenmaer C, Crabtree R, Brudvig G. A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst. Energy & Environmental Science 2011, 4: 2389-2392. DOI: 10.1039/c1ee01037a.Peer-Reviewed Original ResearchThermal stability of [Mn(III)(O)2Mn(IV)(H2O)2(Terpy)2](NO3)3 (Terpy=2,2′:6′,2″-terpyridine) in aqueous solution
Zhang F, Cady C, Brudvig G, Hou H. Thermal stability of [Mn(III)(O)2Mn(IV)(H2O)2(Terpy)2](NO3)3 (Terpy=2,2′:6′,2″-terpyridine) in aqueous solution. Inorganica Chimica Acta 2011, 366: 128-133. DOI: 10.1016/j.ica.2010.10.021.Peer-Reviewed Original ResearchOxo dimerMn4Ca clusterAqueous solutionThermal stabilitySolar fuel productionOxygen evolution activityFirst fast stepMn valence changeAtomic absorption spectroscopyCatalytic materialsElemental analysisPS IIManganese dioxideAbsorption spectroscopyConversion of waterNovel MnDimer compoundsMn valenceSlow stepFast stepSolid MnThermal decompositionValence changeUnique materialFuel productionAnodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors
Blakemore J, Schley N, Olack G, Incarvito C, Brudvig G, Crabtree R. Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors. Chemical Science 2011, 2: 94-98. DOI: 10.1039/c0sc00418a.Peer-Reviewed Original ResearchWater oxidation catalystsOrganometallic precursorsAnodic depositionRobust water oxidation catalystsLight-driven oxidationInorganic heterogeneous catalystsArtificial photosynthesisWater oxidationCatalyst materialsHeterogeneous catalystsFour-electronAqueous solutionCatalystPhotosystem IIOxidationPrecursorsSustainable sourceElectrodepositionIridiumDepositionMaterialsComplexesReactionOxygenAqua
1993
Formation of a high valent di-μ-oxo manganese dimer in aqueous solution
Manchanda R, Brudvig G, Crabtree R, Sarneski J, Didiuk M. Formation of a high valent di-μ-oxo manganese dimer in aqueous solution. Inorganica Chimica Acta 1993, 212: 135-137. DOI: 10.1016/s0020-1693(00)92318-1.Peer-Reviewed Original Research
1992
Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes. [Erratum to document cited in CA113(18):161042g]
Sarneski J, Thorp H, Brudvig G, Crabtree R, Schulte G. Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes. [Erratum to document cited in CA113(18):161042g]. Journal Of The American Chemical Society 1992, 114: 5907-5907. DOI: 10.1021/ja00040a092.Peer-Reviewed Original Research
1991
The chemistry of high-valent oxomanganese clusters in aqueous solution: A (IV,IV) dimer containing bridging and terminal phosphate ligands
Sarneski J, Didiuk M, Thorp H, Crabtree R, Brudvig G, Faller J, Schulte G. The chemistry of high-valent oxomanganese clusters in aqueous solution: A (IV,IV) dimer containing bridging and terminal phosphate ligands. Journal Of Inorganic Biochemistry 1991, 43: 372. DOI: 10.1016/0162-0134(91)84358-g.Peer-Reviewed Original ResearchChemInform Abstract: Assembly of High‐Valent Oxomanganese Clusters in Aqueous Solution. Redox Equilibrium of Water‐Stable Mn3O4+ 4 and Mn2O3+ 2 Complexes.
SARNESKI J, THORP H, BRUDVIG G, CRABTREE R, SCHULTE G. ChemInform Abstract: Assembly of High‐Valent Oxomanganese Clusters in Aqueous Solution. Redox Equilibrium of Water‐Stable Mn3O4+ 4 and Mn2O3+ 2 Complexes. ChemInform 1991, 22: no-no. DOI: 10.1002/chin.199102283.Peer-Reviewed Original Research
1990
Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes
Sarneski J, Thorp H, Brudvig G, Crabtree R, Schulte G. Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes. Journal Of The American Chemical Society 1990, 112: 7255-7260. DOI: 10.1021/ja00176a027.Peer-Reviewed Original Research