2024
Selecting between Ammonia and Water Oxidation: Electrochemical Oxidation of Ammonia in Water Using an Organometallic–Inorganic Hybrid Anode
Liu H, Jayworth J, Crabtree R, Brudvig G. Selecting between Ammonia and Water Oxidation: Electrochemical Oxidation of Ammonia in Water Using an Organometallic–Inorganic Hybrid Anode. ACS Catalysis 2024, 14: 2842-2846. DOI: 10.1021/acscatal.3c05899.Peer-Reviewed Original ResearchHybrid anodeWater oxidationBlue layerElectrochemical oxidation of ammoniaOxidation of ammoniaElectrochemical oxidationSurface poisoningAqueous solventAmmonia oxidationOptimal operating conditionsAqueous solutionAmbient conditionsE appOperating conditionsAnodeFormation of nitriteOxidationOptimum selectionAmmoniaSolventNitrateNanoclustersDinitrogenElectrodeEcofriendly products
2012
Bioinspired High-Potential Porphyrin Photoanodes
Moore G, Konezny S, Song H, Milot R, Blakemore J, Lee M, Batista V, Schmuttenmaer C, Crabtree R, Brudvig G. Bioinspired High-Potential Porphyrin Photoanodes. The Journal Of Physical Chemistry C 2012, 116: 4892-4902. DOI: 10.1021/jp210096m.Peer-Reviewed Original ResearchPorphyrin radical cationRadical cationPhotoelectrochemical cellsReduction potentialDye-sensitized solar cellsElectrochemical reduction potentialsMetal oxide surfacesRedox coupleAppropriate energeticsElectron mediatorOxidation powerSpectroscopic studiesPhotoelectrochemical measurementsSnO2 nanoparticlesBare anodeVisible regionTerahertz spectroscopic studyReaction centersCationsSolar cellsPhotoanodeAnodeNatural counterpartsConduction bandSensitizers
2011
A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst
Moore G, Blakemore J, Milot R, Hull J, Song H, Cai L, Schmuttenmaer C, Crabtree R, Brudvig G. A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst. Energy & Environmental Science 2011, 4: 2389-2392. DOI: 10.1039/c1ee01037a.Peer-Reviewed Original Research