Proton-Coupled Electron Transfer from Electrodes to Myoglobin in Ordered Biomembrane-like Films
Nassar A, Zhang Z, Hu N, Rusling J, Kumosinski T. Proton-Coupled Electron Transfer from Electrodes to Myoglobin in Ordered Biomembrane-like Films. The Journal Of Physical Chemistry B 1997, 101: 2224-2231. DOI: 10.1021/jp962896t.Peer-Reviewed Original ResearchElectron transferProton-coupled electron transferElectron transfer rate constantDidodecyldimethylammonium bromideOne-electron reductionHeme iron ligationElectroactive surface concentrationTransfer rate constantHeme protein myoglobinThin liquid crystal filmsAssociated with protonationProtonation of histidine residuesSoret band absorbancePK a1Protonated formLiquid crystal filmsProtonation equilibriaHeme pocketProximal histidineDistal histidineIron ligationProtein myoglobinKinetic conformerRate constantsCrystal films
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