Molecular Design of a Discrete Oligosaccharide-block-Oligodimethylsiloxane System: Toward Microphase Separation with 1 nm Domain Size and Angstrom-Scale Size Control
Nishimura T, Lee C, Nunokawa R, Cheng Y, Li F, Yamamoto T, Tajima K, Borsali R, Chen H, Satoh T, Isono T. Molecular Design of a Discrete Oligosaccharide-block-Oligodimethylsiloxane System: Toward Microphase Separation with 1 nm Domain Size and Angstrom-Scale Size Control. Macromolecules 2024, 58: 266-278. DOI: 10.1021/acs.macromol.4c02262.Peer-Reviewed Original ResearchBlock copolymersDegree of polymerizationMicrophase-separated lamellar structureThiol-ene reactionSmall-angle X-ray scatteringX-ray scatteringMolecular weight distributionDimethylsiloxane unitsSynthetic accessibilityMolecular designLinker structureAngstrom-scaleMicrophase separationStructural stabilityPolymerizationLamellar structurePolymerization degreeOligodimethylsiloxaneWeight distributionDomain sizeSize controlMonomeric glucoseMicrophaseCopolymersStructure
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