2011
Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer-Sphere Pathway
Dobereiner GE, Nova A, Schley ND, Hazari N, Miller SJ, Eisenstein O, Crabtree RH. Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer-Sphere Pathway. Journal Of The American Chemical Society 2011, 133: 7547-7562. PMID: 21510610, DOI: 10.1021/ja2014983.Peer-Reviewed Original ResearchMild conditionsHomogeneous iridium catalystN-heterocyclic compoundsOuter-sphere mechanismOuter-sphere pathwayInner-sphere mechanismHydrogenation of quinolineUnprecedentedly mild conditionsIridium hydrideIridium-catalyzed hydrogenationCoordination geometryLigand setUnhindered substratesCatalyst precursorsSequential protonCatalytic experimentsCatalytic reactionIridium catalystDFT calculationsDihydride complexCatalyst activityDFT studyHydride transferMechanistic proposalComplex show
2004
Application of P,N-Sulfinyl Imine Ligands to Iridium-Catalyzed Asymmetric Hydrogenation of Olefins
Schenkel LB, Ellman JA. Application of P,N-Sulfinyl Imine Ligands to Iridium-Catalyzed Asymmetric Hydrogenation of Olefins. The Journal Of Organic Chemistry 2004, 69: 1800-1802. PMID: 15058921, DOI: 10.1021/jo035675+.Peer-Reviewed Original Research
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