Asymmetric synthesis of chiral amines by highly diastereoselective 1,2-additions of organometallic reagents to N-tert-butanesulfinyl imines
Cogan D, Liu G, Ellman J. Asymmetric synthesis of chiral amines by highly diastereoselective 1,2-additions of organometallic reagents to N-tert-butanesulfinyl imines. Tetrahedron 1999, 55: 8883-8904. DOI: 10.1016/s0040-4020(99)00451-2.Peer-Reviewed Original ResearchOrganometallic reagentsTert-butanesulfinyl aldiminesTert-butanesulfinyl iminesAddition of alkylN-tert-butanesulfinyl ketiminesSulfinamide productsSulfinyl iminesChiral aminesAsymmetric synthesisDiastereoselective methodElectronic propertiesAcidic methanolysisIminesAminesAllyl carbanionReagentsAlkenylCarbanionsAlkylArylAldehydesKetiminesAldiminesKetonesSynthesis
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