Ring-opening alternating copolymerization of cyclic anhydrides and isobutylene oxide using organobase catalysts
Sugiyama M, Suzuki R, Ayakawa H, Gao T, Li F, Yamamoto T, Isono T, Satoh T. Ring-opening alternating copolymerization of cyclic anhydrides and isobutylene oxide using organobase catalysts. Polymer Journal 2025, 1-11. DOI: 10.1038/s41428-025-01087-9.Peer-Reviewed Original ResearchRing-opening alternating copolymerizationIsobutylene oxideWell-controlled synthesisCyclic anhydridesSynthesis of polyestersOrganobase catalystCrystalline polyestersStatistical copolymersPhthalic anhydrideNarrow molecular weight distributionPotential side reactionsSynthesis of copolymersMolecular weight distributionMacromolecular designSide reactionsAmorphous polyestersBlock copolymersAnhydridePoly(trimethylene carbonateCatalystEpoxideLow reactivityVersatile structureDiverse structuresWeight distribution
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