Breaking a Molecular Scaling Relationship Using an Iron–Iron Fused Porphyrin Electrocatalyst for Oxygen Reduction
Nishiori D, Menzel J, Armada N, Cruz E, Nannenga B, Batista V, Moore G. Breaking a Molecular Scaling Relationship Using an Iron–Iron Fused Porphyrin Electrocatalyst for Oxygen Reduction. Journal Of The American Chemical Society 2024, 146: 11622-11633. PMID: 38639470, DOI: 10.1021/jacs.3c08586.Peer-Reviewed Original ResearchOxygen reduction reactionBinuclear catalystsElectrophilic characterDesign of efficient electrocatalystsCatalytic turnover frequencySynthetic design strategiesMacrocyclic ligandCoordination sphereLigand designTurnover frequencyElectronic conjugationEfficient electrocatalystsReduction reactionOxygen reductionMolecular scaffoldsCatalystCatalytic centerIron-ironCharged sitesElectrocatalystsElectrocatalysisLigandBioinspired applicationsDesign strategyScaling relationshipsPhotoelectrochemical Urea Synthesis from Nitrate and Carbon Dioxide on GaN Nanowires
Dong W, Menzel J, Ye Z, Navid I, Zhou P, Yang K, Batista V, Mi Z. Photoelectrochemical Urea Synthesis from Nitrate and Carbon Dioxide on GaN Nanowires. ACS Catalysis 2024, 14: 2588-2596. DOI: 10.1021/acscatal.3c04264.Peer-Reviewed Original ResearchAg cocatalystC-N couplingReversible hydrogen electrodeSemiconductor photoelectrodesFaradaic efficiencyHydrogen electrodeReduction reactionSolar lightCatalytic activityGaN nanowiresTheoretical calculationsCocatalystCarbon dioxideOptimal conditionsNanowiresSynthesisConversion to nitriteSelectivity of ureaSynthesize ureaPhotoelectrodePhotoelectrochemicalDioxideUreaNitrateControl experiments